n_H2 = 0,5 mol

Đặt n_Fe = x

n_Zn = y

Fe + 2HCl → FeCl₂ + H₂ (1)

x......2x...........x.............x

Zn + 2HCl → ZnCl₂ + H₂ (2)

y........2y..............y........y

Từ (1)(2) ta có hệ

\(\left\{{}\begin{matrix}56x+65y=29,8\\x+y=0,5\end{matrix}\right.\)

⇒ \(\left\{{}\begin{matrix}x=0,3\\y=0,2\end{matrix}\right.\)

⇒ %_Fe = \(\dfrac{0,3.56.100\%}{29,8}\)\(\approx\)56,38%

⇒ %Zn = \(\dfrac{0,2.65.100\%}{29,8}\)\(\approx\) 43,62%

⇒ C_{M HCl} = \(\dfrac{1}{0,6}\) = \(\dfrac{5}{3}\) (M)

a, \(n_{H_2}=0,25\left(mol\right)\)

Bảo toàn e:

\(2n_{Zn}=2n_{H_2}\Rightarrow n_{Zn}=0,25\left(mol\right)\)

\(\Rightarrow m_{Zn}=16,25\left(g\right)\)

\(\Rightarrow m_{Cu}=13,75\left(g\right)\)

b, \(\%m_{Cu}=\dfrac{13,75}{30}=45,83\%\)

\(\Rightarrow\%m_{Zn}=100\%-45,83\%=54,17\%\)

c, Bảo toàn nguyên tố H:

\(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)

\(\Rightarrow C\%_{HCl}=\dfrac{0,5.36,5}{200}=9,125\%\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ PTHH:Fe+2HCl\to FeCl_2+H_2\\ \Rightarrow n_{HCl}=2n_{H_2}=0,2(mol)\\ a,C_{M_{HCl}}=\dfrac{0,2}{0,1}=2M\\ b,n_{Fe}=n_{H_2}=0,1(mol)\\ \Rightarrow m_{Fe}=0,1.56=5,6(g)\\ \Rightarrow m_{Cu}=20-5,6=14,4(g)\\ c,\%m_{Fe}=\dfrac{5,6}{20}.100\%=28\%\\ \%m_{Cu}=100\%-28\%=72\%\)

PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Fe}\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\\%m_{Fe}=\dfrac{0,1\cdot56}{12}\cdot100\%\approx46,67\%\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{0,2}{0,2}=1\left(M\right)\\\%m_{Cu}=53,33\%\end{matrix}\right.\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Cu không phản ứng

\(nH_2=nFe=\dfrac{2,24}{22,4}=0,1mol\)

\(\rightarrow mFe=0,1.56=5,6gam\)

\(\rightarrow\%mFe=\dfrac{5,6}{12}.100\%=46,\left(6\right)\%\)

\(\rightarrow\%mCu=100\%-46,\left(6\right)\%=53,\left(3\right)\%\)

c)

\(CM_{HCl}=\dfrac{0,1.2}{0,2}=1M\)

a Fe + 2HCl ---> FeCl2 + H2

nH2= 2,24 /22,4=0,1 mol

nFe=nH2=0,1 mol

mFe=0,1.56=5.6 g

mCu=12-5,6=6,4g

%mfe=5,6/12 .100%=46,67

%mCu=100%-46,67%=53,33%

n HCl=0,05 mol

CM ddHCl= 0,2/0,2=1M

a,\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

PTHH: Zn + 2HCl → ZnCl₂ + H₂

Mol:      x                                 x    

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:      y                                 y

Ta có: \(\left\{{}\begin{matrix}65x+56y=30,7\\x+y=0,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,3\left(mol\right)\\y=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\%m_{Zn}=\dfrac{0,3.65.100\%}{30,7}=63,52\%;\%m_{Fe}=100\%-63,52\%=36,48\%\)

b,

PTHH: Zn + 2HCl → ZnCl₂ + H₂

Mol:     0,3     0,6                             

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:     0,2     0,4

n_HCl = 0,6+0,4 = 1 (mol)

\(V_{ddHCl}=\dfrac{1}{2}=0,5\left(l\right)=500\left(ml\right)\)

a) \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(Đặt:n_{Zn}=x\left(mol\right);n_{Fe}=y\left(mol\right)\)

\(n_{H_2}=0,4\left(mol\right)\)

Theo đề ta có hệ \(\left\{{}\begin{matrix}65x+56y=24,2\\x+y=0,4\end{matrix}\right.\)

=> x=0,2 ; y=0,2

\(\%m_{Zn}=\dfrac{0,2.65}{24,2}.100=53,72\%;\%m_{Fe}=46,28\%\)

b)Bảo toàn nguyên tố H: \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)

=> \(V_{HCl}=\dfrac{0,8}{2,5}=0,32\left(l\right)\)

c) \(n_{FeCl_2}=0,2\left(mol\right);n_{ZnCl_2}=0,2\left(mol\right)\)

=> \(CM_{FeCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)

\(CM_{ZnCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)